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There are three elements that influence the tax calculation process in M2E Pro:
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Under the Details section in Selling Policy, you should provide a product tax code (PTC), which is assigned to a taxable item. Walmart uses PTC to automatically calculate taxes on each sale based on the item sold and delivery location.
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Under the Order Tax Settings section in your Walmart account configurations, you can select which tax source should be applied during Magento order creation:
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